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class="newsTitle">論在VOCs廢氣處理中催化燃燒的關(guān)鍵作用 </h1>  <div id="hxbdttlfx1" class="newsTime">2021-07-02 13:07 </div>  <div id="hxbdttlfx1" class="newsarticles" data-ename="資訊詳細(xì)描述"><p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;"> VOCs廢氣處理有較多對(duì)策，其治理方式包含源頭減量、正中間操縱和尾端解決等表示現(xiàn)階段，在我國(guó)以尾端治理為主導(dǎo)。尾端治理技術(shù)性一般分成毀壞性處理和收購(gòu)性處理。毀壞性處理關(guān)鍵包含催化燃燒法和集中焚燒處理法。收購(gòu)性處理包含消化吸收法、冷疑法、吸咐法等。收購(gòu)性處理因其方式方法還不完善，成本費(fèi)較高，現(xiàn)階段沒(méi)有規(guī)模性運(yùn)用。</span></span></span></p> <p style="margin: 0cm; text-align: center;"><img id="245" src="/repository/image/1221984f-1ff1-4028-9f78-1053c2378918.jpg" style="width: 474px; height: 287px;" /></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　焚燒處理是立即將VOCs進(jìn)入垃圾焚燒爐中，在爐膛內(nèi)充足燃燒，造成二氧化碳和水。該方式成本費(fèi)較低，應(yīng)用范疇較廣，技術(shù)性路線也較為完善。催化燃燒法是廢氣處理設(shè)備廠家在有機(jī)廢氣燃燒的情況下添加某類催化劑，減少VOCs的著火點(diǎn),使VOCs可以充足燃燒,最后轉(zhuǎn)化成二氧化碳和水，完成直接排放。當(dāng)今常見(jiàn)催化劑類型有Cu、Fe、Ti等非貴重金屬與Pd、Au、Pt等貴重金屬兩類。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　集中焚燒處理法和催化燃燒法在VOCs治理中占有關(guān)鍵影響力，因其溶解空氣氧化完全、治理高效率而獲得廣泛運(yùn)用，在其中催化燃燒法因油灶、環(huán)保節(jié)能、空氣氧化溫度低而獲得廣泛運(yùn)用。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　催化燃燒是一種涉及到氣—固二相的化學(xué)變化，其實(shí)質(zhì)原理為在有氧自由基參加的標(biāo)準(zhǔn)下產(chǎn)生的深層氧化還原反應(yīng)。在反映全過(guò)程中，添加催化劑能夠明顯減少反映需要的活化能，VOCs聚集在催化劑表層，在較低燃燒溫度下產(chǎn)生無(wú)焰燃燒，最后溶解為二氧化碳和水，另外釋放出來(lái)很多的熱。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　在催化劑的功效下，VOCs能夠在較低溫度下充足燃燒，轉(zhuǎn)化成二氧化碳和水，污泥負(fù)荷達(dá)到90%。催化燃燒法具備耗能低、運(yùn)作靠譜平穩(wěn)、無(wú)二次污染等突顯優(yōu)勢(shì)，在歐洲國(guó)家已獲得普遍應(yīng)用推廣。在中國(guó)，催化燃燒法也是解決VOCs的關(guān)鍵方式，其運(yùn)用占比約為55%?，F(xiàn)階段，催化燃燒法早已變成解決VOCs的流行。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　安全型催化燃燒設(shè)備，簡(jiǎn)稱SRCO，是在催化劑的作用下，將VOCs在200～400℃的低溫條件下分解為CO2和H2O，是凈化碳?xì)浠衔锏扔袡C(jī)廢氣、消除惡臭的有效手段之一。在有機(jī)廢氣特別是回收價(jià)值不大的有機(jī)廢氣凈化方面，比如化工、噴漆、絕緣材料、漆包線、涂料生產(chǎn)等行業(yè)應(yīng)用較廣。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　SRCO催化分解裝置由預(yù)處理裝置、預(yù)熱裝置、催化燃燒裝置、防爆裝置組成。環(huán)保SRCO解決了如下問(wèn)題：</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">①解決了安全問(wèn)題。只需要200-400℃即可將幾乎所有的有機(jī)物催化分解，規(guī)避了常規(guī)TO、RTO、RCO等焚燒面臨的火焰安全隱患。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">②解決了凈化效率問(wèn)題。其效率高達(dá)99%以上，其他凈化方式（冷凝回收、TO焚燒、吸附、等離子、光解等）較低、無(wú)法達(dá)標(biāo)排放的問(wèn)題。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">③解決了投入成本問(wèn)題。與RTO常規(guī)RCO等相比SRCO投入成本約為RTO的50%。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">④解決了運(yùn)行成本問(wèn)題。與吸附方法相比，SRCO運(yùn)行成本極低，在濃度大于1000ppm的工況下幾乎可以維持自我正常運(yùn)行，無(wú)需消耗其他能源。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">⑤解決了人員維護(hù)問(wèn)題。整套裝置全部采用PLC自動(dòng)化控制系統(tǒng)，根據(jù)濃度、溫度的變化趨勢(shì)進(jìn)行自動(dòng)調(diào)節(jié)。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　催化劑是催化燃燒法的核心，一種好的催化劑必須具備催化活性高、熱穩(wěn)定性好、強(qiáng)度高、壽命長(zhǎng)等特性。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">1、活性高。催化劑的活性好壞直接影響催化燃燒的化學(xué)轉(zhuǎn)化率。而轉(zhuǎn)化率不僅與催化活性材料自身的活性有關(guān)，而且與催化載體的物理形狀有著直接關(guān)系。所以，在選擇適應(yīng)的催化活性材料的同時(shí)，還必須考慮催化載體的物理形狀，保證催化劑有較高的活性，達(dá)到催化燃燒凈化的目的。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">2、熱穩(wěn)定性好。由于廢氣的溫度隨時(shí)變化，如果催化劑不能適應(yīng)一定范圍內(nèi)的溫度變化，催化劑的性能就會(huì)下降，凈化效率就會(huì)降低。因此，催化劑必須具備適應(yīng)一定范圍內(nèi)的溫度變化。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">3、強(qiáng)度高。在催化燃燒過(guò)程中，催化劑往往會(huì)因高溫、振動(dòng)和氣流等因素的作用，使催化劑產(chǎn)生破裂和磨損，破裂和磨損會(huì)造成催化劑的活性降低，增加催化劑床層的壓降，影響凈化效果。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">4、壽命長(zhǎng)。催化活性材料大都比較昂貴，所以，設(shè)計(jì)時(shí)選用催化劑時(shí)應(yīng)盡量使用壽命較長(zhǎng)的催化劑。</span></span></span></p> <p style="margin:0cm; text-align:justify"><span style="font-family:Microsoft YaHei;"><span style="line-height:2;"><span style="font-size:16px;">　　優(yōu)選稀有金屬催化劑包含Sc、La、Ce、Pr等稀有金屬元素，因多種活性組分之間的協(xié)同作用，有利于催化劑酸性位點(diǎn)的增加，氧化物流動(dòng)性增加，催化活性增強(qiáng)，因而表現(xiàn)出較好的催化性能。金屬原料易于獲得且成本低，因而更加適用于工業(yè)VOCs的催化燃燒。此外，稀有金屬氧化物還具有使用壽命長(zhǎng)、穩(wěn)定性好、再生能力強(qiáng)、易于形成很多不同尺寸和形狀的金屬氧化物等優(yōu)點(diǎn)。</span></span></span></p> </div>  <div id="hxbdttlfx1" class="e_box d_pcDom p_PrevAndNext " data-ename="上一篇、下一篇信息區(qū)" style="display:none;"> <div id="hxbdttlfx1" class="e_box p_previewBox"> <span id="hxbdttlfx1" class="i_title"><span id="hxbdttlfx1" class="i_pageUpTitle">上一個(gè)</span> </span> <a href="/news/18.html" data-ename="上一篇信息區(qū)"> <span id="hxbdttlfx1" class="p_PreviewTitle">制藥工業(yè)過(guò)程中有機(jī)廢氣的治理技術(shù) </span> </a> </div>  <div id="hxbdttlfx1" class="e_box p_nextBox"> <span id="hxbdttlfx1" class="i_title">下一篇 </span> <a href="/news/16.html" data-ename="下一篇標(biāo)題"> <span id="hxbdttlfx1" class="p_PreviewTitle">2021年中國(guó)VOCs治理產(chǎn)業(yè)市場(chǎng)調(diào)研及投資前景深度研究報(bào)告 </span> </a> </div> </div>   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